One-dimensional Complex {[Cu(medpt)][Ag(CN)2]2}n (medpt = N,N-bis-(3-aminopropyl)methylamine)

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dc.contributor.author Mamulová Kutláková, Kateřina
dc.contributor.author Smékal, Zdeněk
dc.contributor.author Neels, Antonia
dc.date.accessioned 2009-09-24T08:09:17Z
dc.date.available 2009-09-24T08:09:17Z
dc.date.issued 2009
dc.identifier.citation Acta Chimica Slovenica. 2009, Vol. 56, No. 2, s. 297-300. en
dc.identifier.issn 1318-0207
dc.identifier.issn 1580-3155
dc.identifier.uri http://hdl.handle.net/10084/76053
dc.description.abstract The novel compound, {[Cu(medpt)][Ag(CN)2]2}n (medpt = N,N-bis-(3-aminopropyl)methylamine), was isolated from a reaction mixture containing Cu(ClO4)2 · 6H2O, medpt and K[Ag(CN)2]. The new complex was characterized by IR spectroscopy, magnetochemical studies and by X-ray single crystal diffraction. The structure contains [Cu(medpt)]2+ units being bridged by [Ag(CN)2]– units resulting in chains of the composition [–μ–CN–Cu(medpt)–μ–NC–Ag–]n, and dicyanoargentate anions. Ag...Ag interactions link free [Ag(CN)2]– anions to the chain. The copper(II) atom is five coordinated to two cyanide-nitrogen and three medpt-nitrogen atoms in a distorted square-pyramidal arrangement. en
dc.format.extent 252286 bytes cs
dc.format.mimetype application/pdf cs
dc.language.iso en en
dc.publisher Slovenian Chemical Society en
dc.relation.ispartofseries Acta Chimica Slovenica en
dc.relation.uri http://acta.chem-soc.si/56/56-2-297.pdf en
dc.subject Copper(II) complexes en
dc.subject dicyanoargentates(I) en
dc.subject cyano-bridged complexes en
dc.subject X-ray structure analysis en
dc.title One-dimensional Complex {[Cu(medpt)][Ag(CN)2]2}n (medpt = N,N-bis-(3-aminopropyl)methylamine) en
dc.type Article en
dc.identifier.location Není ve fondu ÚK en
dc.rights.access restrictedAccess
dc.type.version publishedVersion
dc.identifier.wos 000267424400002

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