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dc.contributor.authorMamulová Kutláková, Kateřina
dc.contributor.authorSmékal, Zdeněk
dc.contributor.authorNeels, Antonia
dc.date.accessioned2009-09-24T08:09:17Z
dc.date.available2009-09-24T08:09:17Z
dc.date.issued2009
dc.identifier.citationActa Chimica Slovenica. 2009, Vol. 56, No. 2, s. 297-300.en
dc.identifier.issn1318-0207
dc.identifier.issn1580-3155
dc.identifier.urihttp://hdl.handle.net/10084/76053
dc.description.abstractThe novel compound, {[Cu(medpt)][Ag(CN)2]2}n (medpt = N,N-bis-(3-aminopropyl)methylamine), was isolated from a reaction mixture containing Cu(ClO4)2 · 6H2O, medpt and K[Ag(CN)2]. The new complex was characterized by IR spectroscopy, magnetochemical studies and by X-ray single crystal diffraction. The structure contains [Cu(medpt)]2+ units being bridged by [Ag(CN)2]– units resulting in chains of the composition [–μ–CN–Cu(medpt)–μ–NC–Ag–]n, and dicyanoargentate anions. Ag...Ag interactions link free [Ag(CN)2]– anions to the chain. The copper(II) atom is five coordinated to two cyanide-nitrogen and three medpt-nitrogen atoms in a distorted square-pyramidal arrangement.en
dc.format.extent252286 bytescs
dc.format.mimetypeapplication/pdfcs
dc.language.isoenen
dc.publisherSlovenian Chemical Societyen
dc.relation.ispartofseriesActa Chimica Slovenicaen
dc.relation.urihttp://acta.chem-soc.si/56/56-2-297.pdfen
dc.subjectCopper(II) complexesen
dc.subjectdicyanoargentates(I)en
dc.subjectcyano-bridged complexesen
dc.subjectX-ray structure analysisen
dc.titleOne-dimensional Complex {[Cu(medpt)][Ag(CN)2]2}n (medpt = N,N-bis-(3-aminopropyl)methylamine)en
dc.typearticleen
dc.identifier.locationNení ve fondu ÚKen
dc.rights.accessrestrictedAccess
dc.type.versionpublishedVersion
dc.identifier.wos000267424400002


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