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dc.contributor.authorKulhánková, Lenka
dc.contributor.authorČapková, Pavla
dc.contributor.authorDe Valle, Veronika Ramirez
dc.contributor.authorPoyato, Juan
dc.contributor.authorPérez-Rodríguez, Jose Luis
dc.contributor.authorLerf, Anton
dc.date.accessioned2008-12-02T07:25:26Z
dc.date.available2008-12-02T07:25:26Z
dc.date.issued2008
dc.identifier.citationJournal of molecular modeling. 2008, vol. 14, no. 12, p. 1183-1189.en
dc.identifier.issn1610-2940
dc.identifier.issn0948-5023
dc.identifier.urihttp://hdl.handle.net/10084/70296
dc.description.abstractMolecular modeling using empirical force field revealed the differences between the surface and interlayer arrangement of the dye guest molecules in vermiculite intercalated with the divalent methyl viologen cation (MV2+). Conformation and anchoring of MV2+ cations on the silicate layer in the interlayer space of vermiculite host structure is different from that on the crystal surface. A preferential position has been found for the anchoring of guests on the silicate layer. Anyway the arrangement of guests in the interlayer space as well as on the crystal surface exhibits a high degree of disorder due to a certain flexibility in guest molecules arrangement and first of all due to the presence of water molecules in the interlayer space. The presence of water disturbs not only the regularity in guest positions and orientations but also in conformation of guest molecules in the interlayer space of the host structure.en
dc.language.isoenen
dc.publisherSpringeren
dc.relation.ispartofseriesJournal of molecular modelingen
dc.relation.urihttp://dx.doi.org/10.1007/s00894-008-0369-xen
dc.subjectmolecular modelingen
dc.subjectmethyl viologenen
dc.subjectMV2+en
dc.subjectvermiculiteen
dc.titleSurface and interlayer structure of vermiculite intercalated with methyl viologenen
dc.typearticleen
dc.identifier.locationNení ve fondu ÚKen
dc.identifier.doi10.1007/s00894-008-0369-x
dc.identifier.wos000260376100007


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