dc.contributor.author | Praus, Petr | |
dc.contributor.author | Blahutová, Markéta | |
dc.date.accessioned | 2006-11-08T13:09:38Z | |
dc.date.available | 2006-11-08T13:09:38Z | |
dc.date.issued | 2001 | |
dc.identifier.citation | Fresenius' Journal of Analytical Chemistry. 2001, vol. 369, no. 5, p. 466-468. | en |
dc.identifier.issn | 0937-0633 | |
dc.identifier.issn | 1432-1130 | |
dc.identifier.uri | http://hdl.handle.net/10084/57960 | |
dc.language.iso | en | en |
dc.publisher | Springer | en |
dc.relation.ispartofseries | Fresenius' Journal of Analytical Chemistry | en |
dc.relation.uri | https://doi.org/10.1007/s002160000620 | en |
dc.title | Simultaneous determination of Fe(II) and Fe(III) in waters by capillary isotachophoresis | en |
dc.type | article | en |
dc.identifier.location | Není ve fondu ÚK | en |
dc.description.abstract-en | An ITP method for the simultaneous determination of Fe(II) and Fe(III) in waters, based on separation of their EDTA and fluoride complexes, respectively, was developed. The leading electrolyte used consists of chlorides, La(III) as co-counter ion and is buffered with p-alanine to pH = 3.5. The terminating electrolyte contains caproic acid and L-histidine (pH = 4.5). The method was validated and tested with samples of artificial, ground and treated water with good results, comparable to those obtained by other analytical techniques. Fe(II) and Fe(III) up to 20 mg/L were measured with an RSD = 1.4-1.5% and detection and determination limits of 0.8-0.9 and 3.0-3.5 mg/L, respectively. The ITP method can be recommended for routine utilization in hydroanalytical laboratories. | en |
dc.identifier.doi | 10.1007/s002160000620 | |
dc.identifier.wos | 000167535900015 | |