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dc.contributor.authorPavlát, Petr
dc.contributor.authorHlaváč, Jan
dc.contributor.authorBekárek, Vojtěch
dc.date.accessioned2007-08-30T08:25:48Z
dc.date.available2007-08-30T08:25:48Z
dc.date.issued1998
dc.identifier.citationChemical Papers. 1998, vol. 52, no. 4, p. 226-229.en
dc.identifier.issn0366-6352
dc.identifier.issn1336-9075
dc.identifier.urihttp://hdl.handle.net/10084/62355
dc.language.isoenen
dc.publisherChemický ústav Slovenskej akadémie vieden
dc.relation.ispartofseriesChemical Papersen
dc.titleSolvent effect on electronic and vibrational spectra of N-methyl-2-nitroaniline and N-methyl-4-nitroanilineen
dc.typearticleen
dc.identifier.locationNení ve fondu ÚKen
dc.description.abstract-enMedium effect on the long-wave absorption maximum (vapour state and 35 solvents) and N-H stretching vibration (26 solvents) of the title compounds was measured and analyzed by the Reichardt, Taft-Kamlet, and PS tela methods, and by the methods of Onsanger's and Born's functions of relative permittivity and refractive index. Except the Reichardt method the applicability of the methods is satisfactory. Performed analysis points to the effect of only nonspecific interactions on the electronic spectrum of N-methyl-2-nitroaniline, effects of acidity and basicity of solvents being meaningless. The N-H stretching vibration of N-methyl-2-nitroaniline is affected by refractive index of medium only.en
dc.identifier.wos000076175900009


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