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dc.contributor.authorBalucani, Nadia
dc.contributor.authorLeonori, Francesca
dc.contributor.authorNevrlý, Václav
dc.contributor.authorFalcinelli, Stefano
dc.contributor.authorBergeat, Astrid
dc.contributor.authorStranges, Domenico
dc.contributor.authorCasavecchia, Piergiorgio
dc.date.accessioned2015-01-07T15:01:21Z
dc.date.available2015-01-07T15:01:21Z
dc.date.issued2014
dc.identifier.citationChemical Physics Letters. 2014, vol. 602, p. 58-62.cs
dc.identifier.issn0009-2614
dc.identifier.issn1873-4448
dc.identifier.urihttp://hdl.handle.net/10084/106258
dc.description.abstractThe O + CH3CCH reaction has been investigated in crossed molecular beam experiments at a collision energy of 38.7 kJ mol−1. Product angular and translational energy distributions have been measured for the H- and CH3-displacement channels and their relative branching ratio has been determined. The CH3-displacement channel is more important (by a factor of 3) than the H-displacement channel. This is not explained by a preference for the addition on the substituted acetylenic carbon atom, but rather by the different tendencies of the two addition intermediates CH3CCOH and CH3COCH to undergo intersystem crossing to the underlying singlet potential energy surface.cs
dc.language.isoencs
dc.publisherElseviercs
dc.relation.ispartofseriesChemical Physics Letterscs
dc.relation.urihttps://doi.org/10.1016/j.cplett.2014.04.016cs
dc.titleReaction dynamics and relative yields of the H- and CH3-displacement channels in the O + CH3CCH reactioncs
dc.typearticlecs
dc.identifier.doi10.1016/j.cplett.2014.04.016
dc.type.statusPeer-reviewedcs
dc.description.sourceWeb of Sciencecs
dc.description.volume602cs
dc.description.lastpage62cs
dc.description.firstpage58cs
dc.identifier.wos000336032700011


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