Source apportionment of magnetite particles in roadside airborne particulate matter

Abstract

Exposure to airborne particulate matter (PM) is associated with pulmonary, cardiovascular and neurological problems. Magnetite, a mixed Fe2+/Fe3+ oxide, is ubiquitous and abundant in PM in urban environments, and might play a specific role in both neurodegeneration and cardiovascular disease. We collected samples of vehicle exhaust emissions, and of heavily-trafficked roadside and urban background dusts from Lancaster and Birmingham, U.K. Then, we measured their saturation magnetic remanence and used magnetic component analysis to separate the magnetite signal from other contributing magnetic components. Lastly, we estimated the contributions made by specific traffic-related sources of magnetite to the total airborne magnetite in the roadside environment. The concentration of magnetite in exhaust emissions is much lower (3-14 x lower) than that in heavily-trafficked roadside PM. The magnetite concentration in petrol-engine exhaust emissions is between similar to 0.06 and 0.12 wt%; in diesel-engine exhaust emissions similar to 0.08-0.18 wt%; in background dust similar to 0.05-0.20 wt% and in roadside dust similar to 0.18-0.95 wt%. Here, we show that vehicle brake wear is responsible for between similar to 68 and 85% of the total airborne magnetite at the two U.K. roadside sites. In comparison, diesel-engine exhaust emissions account for similar to 7% - 12%, petrol-engine exhaust emissions for similar to 2% - 4%, and background dust for 6% - 10%. Thus, vehicle brake wear is by far the most dominant source of airborne magnetite in the roadside environment at the two sites examined. Given the potential risk posed, post-inhalation, by ultrafine magnetite and co-associated transition metal-rich particles to human cardiovascular and neurological health, the high magnetite content of vehicle brake wear might need to be reduced in order to mitigate such risk, especially for vulnerable population groups.