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dc.contributor.authorMatějka, Vlastimil
dc.contributor.authorŠupová, Monika
dc.contributor.authorKlemm, Volker
dc.contributor.authorRafaja, David
dc.contributor.authorValášková, Marta
dc.contributor.authorTokarský, Jonáš
dc.contributor.authorLešková, Jana
dc.contributor.authorPlevová, Eva
dc.date.accessioned2010-02-08T11:07:28Z
dc.date.available2010-02-08T11:07:28Z
dc.date.issued2010
dc.identifier.citationMicroporous and Mesoporous Materials. 2010, vol. 129, issues 1-2, p. 118-125.en
dc.identifier.issn1387-1811
dc.identifier.urihttp://hdl.handle.net/10084/78114
dc.description.abstractIn this paper we describe the preparation and characterization of cadmium sulfide (CdS) particles grown on the Mg and Na-vermiculite (MgV, NaV) fractions of less than 40 μm. The Na-vermiculite was prepared in a monoionic full-saturated 12 Ǻ form from MgV. The cadmium vermiculites were prepared by the ion-exchange method. The processes of the interlayer cations exchange with Cd2+ as well as the own formation of CdS particles after the reaction of cadmium vermiculite with hydrogen sulfide (H2S) were studied by using X-ray powder diffraction method, scanning electron microscopy with energy dispersive analysis, infrared spectroscopy, thermogravimetric analysis, transmission electron microscopy, atomic force microscopy and UV–VIS diffuse reflectance spectroscopy. The possible ordering of the CdS in the vermiculite interlayer was proposed using the molecular modeling.en
dc.language.isoenen
dc.publisherElsevieren
dc.relation.ispartofseriesMicroporous and Mesoporous Materialsen
dc.relation.urihttps://doi.org/10.1016/j.micromeso.2009.09.006en
dc.subjectCdSen
dc.subjectvermiculiteen
dc.subjectXRDen
dc.subjectAFMen
dc.subjectTEMen
dc.subjectIR spectroscopyen
dc.subjectmolecular modelingen
dc.titleVermiculite interlayer as a reactor for CdS ultrafine particles preparationen
dc.typearticleen
dc.identifier.locationNení ve fondu ÚKen
dc.identifier.doi10.1016/j.micromeso.2009.09.006
dc.identifier.wos000273862900016


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