Reakce supernukleofilů v přítomnosti titanosilikátů jako katalyzátorů

Abstract

This bachelor thesis deals with the catalyzed reaction between hex-1-ene and hydroxylamine. The reaction was predicted based on an analogy with catalyzed epoxidation of alkenes with hydrogen peroxide. MFI structured TS-1 titanosilicate with microporous, mesoporous or lamellar structure, MFI structured TS-1-TiPl titanosilicate with titanium pillars, MWW structured Ti-MCM-36 with silica pillars titanosilicate and mesoporous titanosilicate molecular sieve Ti-SBA-15 were used as catalysts. The product distribution as well as solvent and catalyst effects were investigated using GC/FID and GC/MS methods. Conversions of hex-1-ene reached up to 71 % in certain conditions.