Application of direct nonlinear regression from single TG curve to compounds undergoing simple and complex thermal decompositions

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dc.contributor.authorRodante, Fabrizio
dc.contributor.authorVecchio, Stefano
dc.contributor.authorSlovák, Václav
dc.date.accessioned2006-10-26T13:21:15Z
dc.date.available2006-10-26T13:21:15Z
dc.date.issued2003
dc.description.abstract-enNonlinear regression of the basic kinetic equation was used to determine kinetic parameters of simple and complex decomposition processes related to some pesticides and pharmaceutical substances. The method for this calculation was carried out using a single TG curve. These values were compared with those obtained with model-fitting and model-free methods. Nonlinear regression method is able to define a single mechanism for compounds undergoing one or few steps of decomposition processes. For compounds that undergo many steps of decomposition processes, only the mechanisms of some of them can be hypothesized.
dc.identifier.citationInternational Journal of Chemical Kinetics. 2003, vol. 35, issue 12, p. 611-622.en
dc.identifier.doi10.1002/kin.10157
dc.identifier.issn0538-8066
dc.identifier.issn1097-4601
dc.identifier.locationNení ve fondu ÚKen
dc.identifier.urihttp://hdl.handle.net/10084/57434
dc.identifier.wos000186612000001
dc.language.isoenen
dc.publisherWileyen
dc.relation.ispartofseriesInternational Journal of Chemical Kineticsen
dc.relation.urihttps://doi.org/10.1002/kin.10157en
dc.titleApplication of direct nonlinear regression from single TG curve to compounds undergoing simple and complex thermal decompositionsen
dc.typearticleen

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