New perfluoroalkylated amphiphilic methacrylates bearing sulfinyl group as monomers for biomedical applications: water content and oxygen permeability of their copolymers with DEGMA

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dc.contributor.authorCírkva, Vladimír
dc.contributor.authorDuchek, Jan
dc.contributor.authorKaplánek, Robert
dc.contributor.authorPaleta, Oldřich
dc.contributor.authorMichálek, Jiří
dc.contributor.authorPřádný, Martin
dc.contributor.authorChmelíková, Dana
dc.contributor.authorWichterlová, Jana
dc.date.accessioned2007-06-28T12:16:38Z
dc.date.available2007-06-28T12:16:38Z
dc.date.issued2006
dc.description.abstract-enPerfluoroalkylated methacrylates 7a–c bearing sulfinyl group within a straight-chain ester group, i.e. CH2=C(CH3)CO2CH2CH2S(O)–CH2CH2CF2(CF2CF2)nCF3 (n = 1–3) were prepared by two alternative synthetic sequences from 2-[(polyfluoroalkyl)sulfanyl]ethanols HOCH2CH2SCH2CH2CF2(CF2CF2)nCF3 (n = 1–3) in overall yields of 88–91%. Copolymers of 7a–c with diethylene glycol methacrylate (DEGMA) prepared in bulk under radical conditions display high transparency, increased water content and good oxygen permeability properties, which are advantageous for their application in ophthalmology and as prosthetic materials.en
dc.identifier.citationEuropean Journal of Medicinal Chemistry. 2006, vol. 41, issue 11, p. 1320-1326.en
dc.identifier.doi10.1016/j.ejmech.2006.06.003
dc.identifier.issn0223-5234
dc.identifier.locationNení ve fondu ÚKen
dc.identifier.urihttp://hdl.handle.net/10084/60821
dc.identifier.wos000242454100011
dc.language.isoenen
dc.publisherElsevieren
dc.relation.ispartofseriesEuropean Journal of Medicinal Chemistryen
dc.relation.urihttp://dx.doi.org/10.1016/j.ejmech.2006.06.003en
dc.subjectpoly(fluoroalkylsulfinyl methacrylates)en
dc.subjectDEGMA copolymersen
dc.subjectwettability of fluoroalkyl methacrylate copolymersen
dc.subjectoxygen permeability of fluorinated polymersen
dc.titleNew perfluoroalkylated amphiphilic methacrylates bearing sulfinyl group as monomers for biomedical applications: water content and oxygen permeability of their copolymers with DEGMAen
dc.typearticleen

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