Enhancing aromatics and olefins yields in thermo-catalytic pyrolysis of LDPE over zeolites: Role of staged catalysis and acid site density of HZSM-5

Abstract

The present work deals with the thermo-catalytic pyrolysis of LDPE (low-density polyethylene) in lab-scale one-and two-stage test rigs over HZSM-5 catalysts featuring different acid site densities. In the first part of this work, the influence of catalyst-to-feed ratio and temperature (in conjunction with the acid site density of HZSM-5) on the product distribution was studied with an aim to identify the optimum operating conditions for the enhanced production of aromatics and light olefins. For this purpose, one-stage thermo-catalytic pyrolysis was performed in which catalysts were mixed with LDPE pellets for in-situ catalysis. In the one-stage catalytic pyrolysis, the catalyst sample with the highest acid site density gave the highest concentration of aromatics (ca. 55%) in the pyrolysis oil with a mono-aromatics fraction of over 50% that consisted mainly of BTEX (benzene, toluene, ethylbenzene and xylenes) compounds. The highest C-2-C-4 olefins concentration (ca. 65%) in the pyrolysis gas was obtained when the sample with the lowest acid site density was used. In the two-stage catalytic pyrolysis (ex-situ catalysis), the concentration of aromatics in the pyrolysis oil reached over 77% with a mono-aromatics fraction of ca. 72% that contained mainly BTEX compounds, when the most acidic catalyst was used. When the catalyst with the lowest number of strong acid sites was employed, the high content of C-2-C-4 olefins in the pyrolysis gas remained almost independent of the reactor configuration. These findings might provide important new insights for the chemical recycling of plastic wastes.